Tuesday, March 30, 2010
Not all diamonds that are found on Earth originated here. A type of diamond called carbonado that is found in South America and Africa may have been deposited there via an asteroid impact (not formed from the impact) over 3 billion years ago. These diamonds may have formed in the intrastellar environment, but as of 2008, there was no scientific consensus on how carbonado diamonds formed. Presolar grains in many meteorites found on Earth contain nanodiamonds of extraterrestrial origination, probably formed in supernovas. Scientific evidence shows that white dwarf stars have a core of crystallized carbon and oxygen nuclei. The largest of these found in the whole universe so far, BPM 37093, is located 50 light-years (4.7×1014 km) away in the constellation Centaurus. A news release from the Harvard-Smithsonian Center for Astrophysics described that the 2,500-mile (4,000 km)-wide stellar core as a diamond.
Labels: Extraterrestrial formation
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Monday, March 8, 2010
Diamond and graphite are two different allotropes of carbon: pure forms of the same element that differ in structure.
Being a form of carbon, diamond oxidizes in air if it is heated over 700 °C. In the absence of oxygen, for e.g. in a flow of high-purity argon gas, diamond can be heated up to about 1700 °C. Its surface blackens, yet it can be recovered by re-polishing. At high pressure diamond can be heated up to 2500 °C, and a report published in 2009 suggests that diamond can withstand temperatures of 3000 °C and above.
Diamonds are carbon crystals that usually form deep within the Earth under high temperatures and extreme pressures. At surface air pressure, diamonds are not as stable as graphite, and so the decay of diamond is thermodynamically favorable (δH = −2 kJ / mol). So, contrary to De Beers' ad campaign extending from 1948 to at least 2006 under the slogan "A diamond is forever”, diamonds are certainly not forever. However, owing to a very large kinetic energy barrier, diamonds are generally metastable; they will not decay into graphite under normal conditions.
Being a form of carbon, diamond oxidizes in air if it is heated over 700 °C. In the absence of oxygen, for e.g. in a flow of high-purity argon gas, diamond can be heated up to about 1700 °C. Its surface blackens, yet it can be recovered by re-polishing. At high pressure diamond can be heated up to 2500 °C, and a report published in 2009 suggests that diamond can withstand temperatures of 3000 °C and above.
Labels: Thermal stability of Diamonds
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